The collection consists of correspondence, manuscripts of her diary, published under the title "Dnevnik, 1899-1906" (New York, 1951), documents (primarily personal), photographs chiefly taken in Manchuria at the turn of the century, and printed materials, especially clippings. The clippings include articles by Rossolimo, articles about her and members of her family, and about subjects of interest to her. The correspondence spans the years 1845-1952 but concentrates around 1951, the year of the publication of "Dnevnik, 1899-1906." Among the correspondents are Georgiĭ V. Adamovich, Vera N. Bunina, Anton and Ksenii︠a︡ Denikin, Georgiĭ P. Fedotov, Vasiliĭ A. Maklakov, among others. The diary raises issues of feminism and describes in detail the life of Russians in Manchuria, especially during the Russo-Japanese War.

The papers include correspondence, manuscripts, documents, printed materials, and photographs. Much of the correspondence concerns "Reka Vremen." Cataloged correspondents are Georgiĭ Adamovich, George Kennan, Vasiliĭ Maklakov, I︠U︡liĭ Margolin, Sofii︠a︡ Pregeĺ Harrison Salisbury, I︠U︡riĭ Terapi︠a︡no, Nikolaĭ Uli︠́a︡nov, and Edmund Wilson. There are manuscripts of several stories by Olǵa, and of her biography of Vladimir; also included are the memoirs of N.N. Savvin about the St. Petersburg Polytechnic Institute. Printed materials include articles about Vladimir and his obituaries. There is a photograph of the "Normandie" coming into an American port in the 1930s.