The papers relate chiefly to the business, financial, real estate, military, civic and personal activities of Nicholas Fish. There are letters from various military figures concerning army provisions during the Revolution, letters relating to lands given to Fish for his services during the war, twenty letters from various individuals to George Clinton (1739-1812), and ten letters to DeWitt Clinton. The Hamilton Fish letters deal with business matters of his father, Nicholas, after his death. There are a few personal letters from several family members and a diary of Nicholas Fish from 1784. The documents consist of real estate and financial matters of the family as well as various petitions on matters of a civic nature

Correspondence, manuscripts of poems, and manuscripts of lectures by Benjamin. The correspondence consists of original letters of Benjamin, typescript and photostatic copies of Benjamin letters in other libraries, and letters to Benjamin from some of his literary contemporaries including Paul Hamilton Hayne, Willis Gaylord Clark, John Lothrop Motley, and Fitz-Greene Halleck. Many of the letters relate to Park Benjamin's lecture tours. There are other family letters and many documents relating to the Benjamin family,and two letterbooks of John Lothrop Motley. Also, a large amount of genealogical material of the Benjamin family, and its related families from the 16th century to the present day. There are also financial records, monographs, clippings, and photographs.

This collection is primarily concerned with Prof. James Renwick and his professional correspondence and papers, both as Professor of Natural Philosophy (Physics) at Columbia College and as a leading engineer. Many certificates of membership in honorary societies are included. There are letters from Washington Irving (1783-1859) to Prof. Renwick and to his mother, Jane Jeffrey Renwick, pertaining to contemporary events and Irving's own activities. The letters to Mrs. Renwick are about the travels and experiences of Irving and Renwick abroad. The collection also covers the affairs of the Prof. Renwick's grandfather, including documents concerning his land grants in New York State, and those of James Armstrong Renwick, including his valedictory address at Columbia College in 1876 and his class reunion in 1916. There are many legal documents, letters, and manuscripts of various members of the Renwick and Brevoort families; among these are Prof. Renwick's notes on his family genealogy and a memoir of Jane Jeffrey Renwick. Correspondents include Clement Clarke Moore, John A. Dix, Martin Van Buren, Secretary of State John Forsyth, and Secretary of the Navy James K. Paulding. There is one letter from Sir Edward Sabine (1788-1883), President of the Royal Society, giving his views on the American Civil War.

Letters written to Gay from political and literary contemporaries such as Horace Greeley, Charles Sumner, and William Bryant; reports in letter form from his reporters at the front during the Civil War; and personal correspondence including many letters from his wife, Elizabeth Neall Gay. Letters written to Mrs. Gay from family friends and business associates including many from her husband. Correspondence of other members of the Gay family including Walter Gay, Sarah Gay, and Allan Gay. Diaries, notebooks, and journals of Sydney Howard Gay.

The records of W.R. Grace & Co. cover the rise of the Grace shipping business from 1864 until World War II. The early correspondence concerns all aspects of the shipping business in New York and South America, mining interests in Peru and Chile, the railroad in Costa Rica, the inter-ocean canal planned for Nicaragua, and political interests throughout Central and South America. There are letter books, correspondence, and scrapbooks of clippings for all aspects of W.R. Grace's career. There are minute books and other documents for more than 50 subsidiary companies owned by W.R. Grace & Co. or by family members. The papers of Joseph Peter Grace (1872-1950) continue the business, family, and philanthropic activities until 1942. There are also 20 reels of motion picture film about the Grace Co. South American interests in the 1950s.